Environmentally Friendly Electroorganic Synthesis Using Solid-Supported Acids and Bases

Solid acids and their use as environmentally friendly catalysts in organic synthesis*

Tightening environmental legislation is driving the fine and speciality chemicals industries to consider alternative processes that avoid the use of conventional mineral acids. The use of heterogeneous catalysts in these processes would vastly simplify catalyst removal, minimizing the amount of waste formed. However, diffusion limitation of liquids within porous solids dictates that effective s...

single-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...

SYNTHESIS AND CHARACTERIZATION OF AN ENVIRONMENTALLY-FRIENDLY HYBRID NANOCOMPOSITE COATING

In this research, a kind of environmentally-friendly inorganic-organic hybrid nanocomposite coating based on silica containing titania/silica core/shell nanoparticles was synthesized and characterized for conservation of facade tiles in historical buildings. The matrix of the composite was prepared by sol-gel process via two methods of ultrasonic and reflux stirring. Tetraethyl orthosilicate (T...

Environmentally friendly methodologies of nanostructure synthesis.

Environmentally friendly synthetic methodologies have gradually been implemented as viable techniques in the synthesis of a range of nanostructures. In this work, we focus on the application of green-chemistry principles to the synthesis of complex metal oxide and fluoride nanostructures. In particular, we describe advances in the use of the molten-salt synthetic methods, hydrothermal protocols...

Environmentally Friendly Synthesis of Polymer-Grafted Nanoparticles